N-(3-Chloro­benzo­yl)-2-nitro­benzene­sulfonamide

نویسندگان

  • P. A. Suchetan
  • Sabine Foro
  • B. Thimme Gowda
  • M. Shet Prakash
چکیده

In the title compound, C(13)H(9)ClN(2)O(5)S, the N-C bond in the C-SO(2)-NH-C segment has a gauche torsion with respect to the S=O bonds. The conformation between the N-H bond and the ortho-nitro group in the sulfonyl benzene ring is syn, and that between the C=O and the meta-Cl atom in the benzoyl ring is anti. The mol-ecule is twisted at the S-N bond, with a torsion angle of 65.41 (38)°. The dihedral angle between the sulfonyl benzene ring and the -SO(2)-NH-C-O segment is 75.0 (1)°, and that between the sulfonyl and the benzoyl benzene ring is 89.1 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O(S) hydrogen bonds.

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منابع مشابه

N-(2-Chloro­benzo­yl)-3-nitro­benzene­sulfonamide

In the mol-ecule of the title compound, C(13)H(9)ClN(2)O(5)S, the dihedral angle between the two aromatic rings is 84.3 (1)°. In the crystal, mol-ecules are linked into chains via N-H⋯O(S) hydrogen bonds.

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N-(3-Chloro­benzo­yl)-3-nitro­benzene­sulfonamide

In the title compound, C(13)H(9)ClN(2)O(5)S, the dihedral angle between the two benzene rings is 83.5 (1)°. In the crystal, mol-ecules are linked via N-H⋯O(S) hydrogen bonds into helical chains running along the b axis.

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N-(2-Chloro­benzo­yl)-2-nitro­benzene­sulfonamide

In the title compound, C(13)H(9)ClN(2)O(5)S, the dihedral angle between the two rings is 71.2 (1)°. The crystal structure features inversion dimers linked by pairs of N-H⋯O(S) hydrogen bonds.

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N-Benzoyl-3-nitro­benzene­sulfonamide

In the title compound, C(13)H(10)N(2)O(5)S, the dihedral angle between the phenyl and benzene rings is 86.7 (1)°. In the crystal, mol-ecules are linked into zigzag C(4) chains running along the b axis via N-H⋯O hydrogen bonds.

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N-(3-Chloro­phen­yl)-2-nitro­benzene­sulfonamide

In the title compound, C(12)H(9)ClN(2)O(4)S, the dihedral angle between the aromatic rings is 73.65 (7)°. The amide H atom shows bifurcated hydrogen bonding, generating an intra-molecular S(7) and an inter-molecular C(4) motif.

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012